Highly crosslinked, chlorine tolerant polymer network entwined graphene oxide membrane for water desalination. Issue 4 (22nd December 2016)

• Record Type: Journal Article
• Authors: Kim, Seungju; Lin, Xiaocheng; Ou, Ranwen; Liu, Huiyuan; Zhang, Xiwang; Simon, George P.; Easton, Christopher D.; Wang, Huanting
• Is Part Of: Journal of materials chemistry. Volume 5:Issue 4(2017)
• Page Start: 1533
• Page End: 1540
• Publication Date: 2016-12-22
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c6ta07350f
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A graphene oxide (GO)–polymer nanocomposite membrane was fabricated by integrating GO nanosheets into a highly crosslinked polymer network on a porous polymer substrate for desalination. Abstract : Graphene and its derivatives are very attractive for constructing membranes for high-efficiency separation applications including water purification and desalination. To develop practical desalination membranes, strictly controlled inter-layer distance of graphene-based laminates and strong adhesion of graphene-based selective layers onto a porous polymer substrate are required to provide high salt rejection properties and desirable mechanical durability with chlorine tolerance in membrane processes. However, there is a difficulty in stabilizing graphene nanosheets as a membrane selective layer for the desalination process and controlling their interlayer distance. In this work, we demonstrate the successful fabrication of a graphene-based thin-film composite membrane by integrating graphene oxide (GO) nanosheets into a highly crosslinked polymer network on a porous polymer substrate. The resulting poly( N -isopropylacrylamide- co-N, N ′-methylene-bisacrylamide) entwined GO thin-film composite membrane has a main GO interlayer spacing of 0.48 nm and a GO–polymer thin film of less than 40 nm thick and shows excellent water flux (25.8 L m −1 h −1 ) and salt rejection (a NaCl rejection of 99.9%), alongside excellent mechanical stability and chlorine tolerance for the forward osmosis process. This polymer network entwined GO thin-film composite can be effectively tailored as a platform material for developing high-performance osmosis desalination membranes for industrial application.