Catalytic decomposition and mechanism of formaldehyde over Pt–Al2O3 molecular sieves at room temperature. Issue 10 (27th February 2017)

• Record Type: Journal Article
• Authors: Zhu, Xiaofeng; Yu, Jiaguo; Jiang, Chuanjia; Cheng, Bei
• Is Part Of: Physical chemistry chemical physics. Volume 19:Issue 10(2017)
• Page Start: 6957
• Page End: 6963
• Publication Date: 2017-02-27
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c6cp08223h
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Al2 O3 molecular sieve supported Pt was prepared for catalytic formaldehyde oxidation at room temperature. Abstract : To overcome the drawbacks of powder-like catalysts in practical application, an Al2 O3 molecular sieve supported Pt (Pt–Al2 O3 ) catalyst was prepared by the impregnation method combined with dilute hydrochloric acid solution pretreatment. The role of the pretreatment solution in catalyst preparation and formaldehyde (HCHO) decomposition over Pt–Al2 O3 catalysts was investigated. The acid solution with pH = 1 was optimal for Pt dispersion on the Al2 O3 surface. The Pt–Al2 O3 catalyst was capable of achieving complete and stable HCHO oxidation at ambient temperature. In addition, the excellent activity for HCHO removal was promoted by the mesoporous structure, large specific surface area and high adsorption ability of Al2 O3 molecular sieves, as determined by N2 -sorption studies. Dioxymethylene (DOM) and formate species were identified as major intermediates by in situ DRIFTS studies. These intermediates were subsequently oxidized into CO2 and H2 O at ambient temperature. Moreover, a possible reaction mechanism of HCHO removal and a regeneration pathway of surface hydroxyls were proposed. This study provides new insights into the preparation of practical, low-cost catalysts for indoor air purification.