Crystal phase- and morphology-controlled synthesis of MoO3 materials. Issue 11 (21st February 2017) - Li, Zhongcheng
Abstract : Mutual transformation of h-MoO3 and α-MoO3 was achieved via a facile hydrothermal method and the crystal phase and morphology of the MoO3 materials were precisely tuned under suitable synthetic conditions. Abstract : The crystal phase and morphology of MoO3 materials were precisely tuned under suitable synthetic conditions and mutual transformation of h-MoO3 and α-MoO3 was achieved via a facile hydrothermal method for the first time. The h-MoO3 microrods with a diameter of 0.5–1.6 μm and length of 2.2–6.1 μm were fabricated with the assistance of NaNO3 using α-MoO3 particles as the precursor. The transformation of h-MoO3 microrods to α-MoO3 nanobelts with a diameter of 150–430 nm and length of 2.1–14.5 μm occurred through hydrothermal techniques at higher temperature. Systematic studies of synthetic parameters revealed that the hexagonal h-MoO3 microrods formed at higher concentration of NaNO3, while h-MoO3 microrods vanished at higher temperature with prolonged time and α-MoO3 nanobelts were exclusively produced. The h-MoO3 microrods exhibited higher catalytic activity in photo-degradation of methylene blue than the α-MoO3 nanobelts. This is ascribed to the weaker fluorescence and reduced bandgap energy of the h-MoO3 microrods than those of the α-MoO3 nanobelts.