Asymmetric cobalt catalysts for hydroboration of 1, 1-disubstituted alkenes. Issue 11 (2nd December 2014)

• Record Type: Journal Article
• Authors: Chen, Jianhui; Xi, Tuo; Ren, Xiang; Cheng, Biao; Guo, Jun; Lu, Zhan
• Is Part Of: Organic chemistry frontiers. Volume 1:Issue 11(2014)
• Page Start: 1306
• Page End: 1309
• Publication Date: 2014-12-02
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c4qo00295d
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1, 1-disubstituted aryl alkenes. These novel IPO ligands will likely be of high value for asymmetric transformations with first-row transition metals. Abstract : Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1, 1-disubstituted aryl alkenes. These novel IPO ligands will likely be of high value for asymmetric transformations with first-row transition metals.