Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters. Issue 3 (16th December 2016)
- Record Type:
- Journal Article
- Title:
- Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters. Issue 3 (16th December 2016)
- Main Title:
- Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters
- Authors:
- Zhang, Chun
Tutkowski, Brandon
DeLuca, Ryan J.
Joyce, Leo A.
Wiest, Olaf
Sigman, Matthew S. - Abstract:
- Abstract : An enantioselective, redox-relay Heck alkenylation of trisubstituted allylic alkenol substrates has been developed. Abstract : An enantioselective, redox-relay Heck alkenylation of trisubstituted allylic alkenol substrates has been developed. This process enables the construction of vicinal stereocenters in high diastereo- and enantioselectivity and allows the formation of enolizable α-carbonyl methyl-substituted stereocenters with no observed epimerization under the reported reaction conditions.
- Is Part Of:
- Chemical science. Volume 8:Issue 3(2017)
- Journal:
- Chemical science
- Issue:
- Volume 8:Issue 3(2017)
- Issue Display:
- Volume 8, Issue 3 (2017)
- Year:
- 2017
- Volume:
- 8
- Issue:
- 3
- Issue Sort Value:
- 2017-0008-0003-0000
- Page Start:
- 2277
- Page End:
- 2282
- Publication Date:
- 2016-12-16
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/SC ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6sc04585e ↗
- Languages:
- English
- ISSNs:
- 2041-6520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3151.490000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1149.xml