Palladium-catalyzed regioselective C–H fluoroalkylation of indoles at the C4-position. Issue 28 (14th March 2017)
- Record Type:
- Journal Article
- Title:
- Palladium-catalyzed regioselective C–H fluoroalkylation of indoles at the C4-position. Issue 28 (14th March 2017)
- Main Title:
- Palladium-catalyzed regioselective C–H fluoroalkylation of indoles at the C4-position
- Authors:
- Borah, Arun Jyoti
Shi, Zhuangzhi - Abstract:
- Abstract : An exclusive catalytic C4-selective fluoroalkylation of indoles with highly active (1 H, 1 H -perfluoroalkyl)mesityliodonium triflate has been described. Abstract : An exclusive catalytic C4-selective fluoroalkylation of indoles with highly active (1 H, 1 H -perfluoroalkyl)mesityliodonium triflate has been described. The key to its high regioselectivity is the appropriate choice of an easily accessible, cheap and removable directing group at the C3 position in the presence of a Pd(OAc)2 catalyst. Besides indole fluoroalkylation, the application of this strategy in other heteroarenes such as benzo[ b ]thiophene is also described.
- Is Part Of:
- Chemical communications. Volume 53:Issue 28(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 28(2017)
- Issue Display:
- Volume 53, Issue 28 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 28
- Issue Sort Value:
- 2017-0053-0028-0000
- Page Start:
- 3945
- Page End:
- 3948
- Publication Date:
- 2017-03-14
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc01274h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1429.xml