Difluoromethylcarbene for iron-catalyzed cyclopropanation. Issue 27 (20th March 2017)
- Record Type:
- Journal Article
- Title:
- Difluoromethylcarbene for iron-catalyzed cyclopropanation. Issue 27 (20th March 2017)
- Main Title:
- Difluoromethylcarbene for iron-catalyzed cyclopropanation
- Authors:
- Duan, Yaya
Lin, Jin-Hong
Xiao, Ji-Chang
Gu, Yu-Cheng - Abstract:
- Abstract : Fe-Catalyzed cyclopropanation of olefins with difluoromethylcarbene generated from sulfonium ylide Ph2 S + –CH − CF2 H with high diastereoselectivity is described. Abstract : Difluoroethylsulfonium salt, Ph2 S + CH2 CF2 H OTf −, was developed into a convenient difluoromethylcarbene reagent for the iron-catalyzed cyclopropanation of terminal olefins, giving various difluoromethyl–cyclopropanes with excellent diastereoselectivities and in high yields.
- Is Part Of:
- Chemical communications. Volume 53:Issue 27(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 27(2017)
- Issue Display:
- Volume 53, Issue 27 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 27
- Issue Sort Value:
- 2017-0053-0027-0000
- Page Start:
- 3870
- Page End:
- 3873
- Publication Date:
- 2017-03-20
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc01636k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1137.xml