Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles. Issue 28 (22nd March 2017)

• Record Type: Journal Article
• Authors: Imada, Yasushi; Yamaguchi, Yusuke; Shida, Naoki; Okada, Yohei; Chiba, Kazuhiro
• Is Part Of: Chemical communications. Volume 53:Issue 28(2017)
• Page Start: 3960
• Page End: 3963
• Publication Date: 2017-03-22
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc00664k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Unactivated alkenes were previously found to be effective carbon nucleophiles for anodic cycloadditions in lithium perchlorate/nitromethane electrolyte solution. Abstract : Unactivated alkenes were previously found to be effective carbon nucleophiles for anodic cycloadditions in lithium perchlorate/nitromethane electrolyte solution. Herein, 7 Li NMR analysis and calorimetric studies clearly illustrate that the entropic effect is essential for these anodic cycloadditions, which has led to the successful screening of novel effective electrolytes.