Two photochromic methylated nicotinohydrazide iodoargentate hybrids. Issue 101 (18th October 2016)

• Record Type: Journal Article
• Authors: Shen, Junju; Wang, Feng; Li, Xiangxia; Yu, Tanlai; Hao, Pengfei; Fu, Yunlong
• Is Part Of: RSC advances. Volume 6:Issue 101(2016)
• Page Start: 98916
• Page End: 98920
• Publication Date: 2016-10-18
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra20084b
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Two methylated nicotinohydrazide iodoargentate hybrids have been synthesized via modulating organic/inorganic ratio, which exhibit rare structure-dependent electron-transfer (ET) photochromism. Abstract : Directed by in situ methylated nicotinohydrazide (MNH 2+ ), two iodoargentate hybrids, {[MNH][Ag3 I5 ]} n (1 ) and {[MNH][Ag7 I9 ]} n (2 ), have been synthesized via modulating the organic/inorganic ratio. They exhibit rare structure-dependent electron transfer (ET) photochromism as confirmed by EPR, XPS, and UV-vis absorption spectra.