Electrochemical and photophysical behavior of 1-naphthol in benzyl-n-hexadecyldimethylammonium 1, 4-bis(2-ethylhexyl)sulfosuccinate large unilamellar vesicles. Issue 23 (25th May 2016)

• Record Type: Journal Article
• Authors: Cobo Solis, Airam K.; Mariano Correa, N.; Molina, Patricia G.
• Is Part Of: Physical chemistry chemical physics. Volume 18:Issue 23(2016)
• Page Start: 15645
• Page End: 15653
• Publication Date: 2016-05-25
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c6cp01979j
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : The behavior of 1-naphthol and its partition process in LUVs formed from a new catanionic surfactant were studied by electrochemical and spectroscopic techniques. Abstract : In the present contribution, 1-naphthol is investigated in large unilamellar vesicles formed from a new catanionic surfactant, benzyl- n -hexadecyldimethylammonium 1, 4-bis(2-ethylhexyl)sulfosuccinate, by electrochemical and spectroscopic techniques. The electrochemical results show that 1-naphthol experiences a partition process between the water phase and the large unilamellar vesicle bilayer phase, which is corroborated by absorption spectroscopic studies at pH = 6.40 and pH = 10.75. Interestingly, studies of 1-naphthol emission in benzyl- n -hexadecyldimethylammonium 1, 4-bis(2-ethylhexyl)sulfosuccinate large unilamellar vesicles at pH = 10.75 and in sodium 1, 4-bis(2-ethylhexyl)sulfosuccinate water solution show that when the 1, 4-bis(2-ethylhexyl)sulfosuccinate moiety is part of the bilayer, the 1, 4-bis(2-ethylhexyl)sulfosuccinate polar head interacts strongly with 1-naphthol, by favoring emission from the excited neutral species resulting in the appearance of a new band close to λ = 355 nm. It seems that the large unilamellar vesicle bilayer of the catanionic vesicle slows down the proton transfer process observed in water, where only emission from 1-naphtholate is detected.