Enantioselective Diels–Alder reaction in the confined space of homochiral metal–organic frameworks. Issue 112 (23rd November 2016)

• Record Type: Journal Article
• Authors: Tanaka, Koichi; Nagase, Shohei; Anami, Taku; Wierzbicki, Michał; Urbanczyk-Lipkowska, Zofia
• Is Part Of: RSC advances. Volume 6:Issue 112(2016)
• Page Start: 111436
• Page End: 111439
• Publication Date: 2016-11-23
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra23740a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A novel homochiral porous MOF synthesized using ( R )-2, 2′-dihydroxy-1, 1′-binaphthyl-4, 4′-dibenzoic acid was shown to be an effective heterogeneous catalyst for asymmetric Diels–Alder reaction between isoprene and N -ethyl maleimide. Abstract : A novel homochiral porous metal–organic framework (MOF) has been synthesized using ( R )-2, 2′-dihydroxy-1, 1′-binaphthyl-4, 4′-dibenzoic acid as the chiral ligand. This MOF acts as an effective heterogeneous catalyst for the enantioselective Diels–Alder reaction between isoprene and N -ethyl maleimide.