2D-cadmium MOF and gismondine-like zinc coordination network based on the N-(2-tetrazolethyl)-4′-glycine linker. (18th March 2015)

• Record Type: Journal Article
• Authors: Salinas-Castillo, Alfonso; Calahorro, Antonio J.; Briones, David; Fairen-Jiménez, David; Gándara, Felipe; Mendicute-Fierro, Claudio; Seco, José M.; Pérez-Mendoza, Manuel; Fernández, Belén; Rodríguez-Diéguez, Antonio
• Is Part Of: New journal of chemistry. Volume 39:Number 5(2015:May)
• Page Start: 3982
• Page End: 3986
• Publication Date: 2015-03-18
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c5nj00011d
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : We have designed and synthesized two new metal-organic-frameworks (MOFs) using the novel N -(2-tetrazolethyl)-4′-glycine spacer (TeGly) 2− . These materials exhibit intense photoluminescence. Abstract : We have designed and synthesized two new metal–organic-frameworks (MOFs) using the novel N -(2-tetrazolethyl)-4′-glycine spacer (TeGly) 2− . We report the in situ formation of cadmium- and zinc-based MOFs using hydrothermal routes. The cadmium-based MOF shows a bi-dimensional network with luminescence emission while the zinc-based MOF exhibits a three-dimensional structure with gismondine topology and intense blue-greenish photoluminescence emission at room temperature in the solid state. In addition, the porosity of the Zn-based MOF has been fully characterized using a combination of computational methods and experimental techniques.