Synthesis, photophysical, electrochemical and single-crystal x-ray diffraction study of (Z)-2-phenyl-3-(5-(4-(thiophen-2-yl)benzo[c][1, 2, 5]thiadiazol-7-yl)thiophen-2-yl)acrylonitrile. Issue 12 (17th June 2016)

• Record Type: Journal Article
• Authors: Bhanvadia, Viraj J.; Patel, Heta A.; Sharma, Neha N.; Patel, Arun L.
• Is Part Of: Synthetic communications. Volume 46:Issue 12(2016)
• Page Start: 1052
• Page End: 1061
• Publication Date: 2016-06-17
• Subjects: Benzothiadiazole -- photophysical properties -- single-crystal x-ray diffraction; Organic compounds -- Synthesis -- Periodicals; Chemistry, Organic; Synthesis; 547.205
• DOI: 10.1080/00397911.2016.1185125
• Languages: English
• ISSNs: 0039-7911

Abstract

ABSTRACT: The optical characteristics, redox properties, thermogravimetric stability and single-crystal X-ray diffraction study of ( Z )-2-phenyl-3-(5-(4-(thiophen-2-yl)benzo[c][1, 2, 5]thiadiazol-7-yl)thiophen-2-yl)acrylonitrile are examined using ultraviolet–visible spectrophotometry, cyclic voltammetry, thermal gravimetric analysis–diffraction scanning calorimetry analysis, single-crystal X-ray diffraction and density functional theory calculations. Evidently, the crystal structure of compound6 is sustained by a number of weak nonconventional intermolecular forces of attraction such as C-H … N, C-H … π donor–acceptor interactions. GRAPHICAL ABSTRACT: