Studying Fast Reaction Kinetics with Online NMR Spectroscopy1. Issue 4 (23rd December 2016)

• Record Type: Journal Article
• Authors: von Harbou, Erik; Behrens, Richard; Berje, Jürgen; Brächer, Alexander; Hasse, Hans
• Other Names: Klemm Elias guestEditor.; Kraume Matthias guestEditor.; Riter Joachim guestEditor.; Sauer Jörg guestEditor.
• Is Part Of: Chemie Ingenieur Technik. Volume 89:Issue 4(2017:Apr.)
• Page Start: 369
• Page End: 378
• Publication Date: 2016-12-23
• Subjects: Micro‐reaction technology -- Online NMR spectroscopy -- Reaction kinetics; Chemical engineering -- Patents -- Periodicals; Chemical engineering -- Periodicals; Chemical industry -- Periodicals; Chemistry, Technical -- Periodicals; 660.05
• DOI: 10.1002/cite.201600068
• Languages: English
• ISSNs: 0009-286X

Abstract

Abstract: A liquid thermostated microreactor Nuclear Magnetic Resonance (NMR) probe head is presented that facilitates the investigation of kinetics of fast reactions. With this setup, reaction kinetics can be studied in a broad temperature (–20 – 100 °C) and pressure range (0 – 60 bar). The setup and NMR probe head are discussed from a reaction engineering standpoint based on experiments and simulations. The microreactor probe head widens significantly the range of applications of online NMR spectroscopy for reaction and process monitoring. Abstract : A liquid thermostated microreactor Nuclear Magnetic Resonance (NMR) probe head is presented that facilitates the investigation of fast reactions. The NMR probe head is discussed from a reaction engineering standpoint based on experiments and simulations. The NMR probe head widens significantly the range of applications of online NMR spectroscopy.