Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1, 2‐Quinone Cycloaddition (SPOCQ). (15th February 2017)
- Record Type:
- Journal Article
- Title:
- Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1, 2‐Quinone Cycloaddition (SPOCQ). (15th February 2017)
- Main Title:
- Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1, 2‐Quinone Cycloaddition (SPOCQ)
- Authors:
- Sen, Rickdeb
Escorihuela, Jorge
van Delft, Floris
Zuilhof, Han - Abstract:
- Abstract: Strain‐promoted oxidation‐controlled cyclooctyne‐1, 2‐quinone cycloaddition (SPOCQ) between functionalized bicyclo[6.1.0]non‐4‐yne (BCN) and surface‐bound quinones revealed an unprecedented 100 % conjugation efficiency. In addition, monitoring by direct analysis in real time mass spectrometry (DART‐MS) revealed the underlying kinetics and activation parameters of this immobilization process in dependence on its microenvironment.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 12(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 12(2017)
- Issue Display:
- Volume 129, Issue 12 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 12
- Issue Sort Value:
- 2017-0129-0012-0000
- Page Start:
- 3347
- Page End:
- 3351
- Publication Date:
- 2017-02-15
- Subjects:
- Cyclooctine -- Massenspektrometrie -- Metallfreie Klick-Chemie -- Oberflächenchemie -- Reaktionskinetik
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201612037 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 2051.xml