Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans‐[Ru(NHC)4H2] through a Concerted Nucleophilic Ru−H Attack Pathway. (9th January 2017)
- Record Type:
- Journal Article
- Title:
- Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans‐[Ru(NHC)4H2] through a Concerted Nucleophilic Ru−H Attack Pathway. (9th January 2017)
- Main Title:
- Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans‐[Ru(NHC)4H2] through a Concerted Nucleophilic Ru−H Attack Pathway
- Authors:
- Cybulski, Mateusz K.
McKay, David
Macgregor, Stuart A.
Mahon, Mary F.
Whittlesey, Michael K. - Abstract:
- Abstract: The efficient and highly selective room temperature hydrodefluorination (HDF) of fluoroarenes by the trans‐[Ru(IMe4 )4 H2 ] catalyst, 3, is reported. Mechanistic studies show3 acts directly in catalysis without any ligand dissociation and DFT calculations indicate a concerted nucleophilic attack mechanism. The calculations fully account for the observed selectivities which corroborate earlier predictions regarding the selectivity of HDF.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 6(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 6(2017)
- Issue Display:
- Volume 129, Issue 6 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 6
- Issue Sort Value:
- 2017-0129-0006-0000
- Page Start:
- 1537
- Page End:
- 1541
- Publication Date:
- 2017-01-09
- Subjects:
- Dichtefunktionalrechnungen -- Homogene Katalyse -- Hydrodefluorierung -- N-Heterocyclische Carbene -- Ruthenium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201610820 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 355.xml