Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3 and iodine. Issue 25 (10th March 2017)
- Record Type:
- Journal Article
- Title:
- Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3 and iodine. Issue 25 (10th March 2017)
- Main Title:
- Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3 and iodine
- Authors:
- Beniazza, Redouane
Douarre, Maxime
Lastécouères, Dominique
Vincent, Jean-Marc - Abstract:
- Abstract : Iodotrifluoromethylation of alkenes is effectively conducted by combining benzophenone, "black light", isopropanol and Togni reagent1 as the source of both the CF3 group and iodine atom. Abstract : A light-promoted methodology for the iodotrifluoromethylation of alkenes was developed. For the first time a Togni reagent was exploited as the source of both the CF3 group and iodine atom. Preliminary mechanistic studies suggest that both CF3 I and 2-iodobenzoic acid are direct sources of the iodine atom that is transferred to the products.
- Is Part Of:
- Chemical communications. Volume 53:Issue 25(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 25(2017)
- Issue Display:
- Volume 53, Issue 25 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 25
- Issue Sort Value:
- 2017-0053-0025-0000
- Page Start:
- 3547
- Page End:
- 3550
- Publication Date:
- 2017-03-10
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc00214a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1425.xml