Effect of Individualized Cellulose Fibrils on Properties of Poly(Methyl Methacrylate) Composites. Issue 9 (1st September 2016)

• Record Type: Journal Article
• Authors: Islam, Mohammad Tajul; Montarsolo, Alessio; Zoccola, Marina; Canetti, Maurizio; Cacciamani, Adriana; Bertini, Fabio
• Is Part Of: Journal of macromolecular science. Volume 55:Issue 9(2016)
• Page Start: 867
• Page End: 883
• Publication Date: 2016-09-01
• Subjects: Composites -- cellulose fibrils -- poly(methyl methacrylate) -- thermal degradation; Polymerization -- Periodicals; Polymers -- Periodicals; 530.413
• DOI: 10.1080/00222348.2016.1207589
• Languages: English
• ISSNs: 0022-2348

Abstract

ABSTRACT: Cellulose fibrils were manufactured from flax fibers using chemical treatments followed by cryo-crushing and ultrasonication techniques. The fibrils, consisting mainly of cellulose free from lignin, pectin and hemicellulose, were exploited as a biofiller in preparing poly(methyl methacrylate) (PMMA) matrix composites. The effects of incorporating cellulose fibrils on the physical and mechanical properties of the polymer matrix were investigated. In particular, the influence of the fibrils on the thermal stability and degradation of the composites was studied by means of thermogravimetric analysis carried out in both inert and oxidative atmospheres. The runs performed under air flow revealed the efficiency of the cellulose fibrils in delaying the polymer decomposition during thermal oxidation. The weight loss was slowed down in the composites of all compositions and the temperature of degradation increased with increasing the amount of the fibrils. The combustion properties of the fibril-based composites were evaluated by means of pyrolysis combustion flow calorimetry. The addition of cellulose fibrils into the PMMA matrix resulted in a noticeable decrease of the primary combustion parameters.