Morphology evolution of primary Mg2Si in Al–20Mg2Si–0.1Ca alloys prepared with various solidification cooling rates. Issue 12 (8th March 2017)

• Record Type: Journal Article
• Authors: Wang, Hui-Yuan; Yu, Hong-Chen; Li, Chao; Zha, Min; Wang, Cheng; Jiang, Qi-Chuan
• Is Part Of: CrystEngComm. Volume 19:Issue 12(2017)
• Page Start: 1680
• Page End: 1688
• Publication Date: 2017-03-08
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c7ce00028f
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : The morphology evolution of primary Mg2 Si in the Al–20Mg2 Si–0.1Ca alloy was investigated by a mould temperature-controlled solidification technique at various solidification cooling rates. Abstract : The morphology evolution of primary Mg2 Si in the Al–20Mg2 Si–0.1Ca alloy was investigated by a mould temperature-controlled solidification technique at various solidification cooling rates. It is found that by lowering the pre-set mould temperature, i.e. increasing the cooling rates, the influence of external factors, i.e. the adsorption of Ca atoms on {100} facets, on the morphology evolution of primary Mg2 Si can be strengthened, leading to primary Mg2 Si with varying morphologies. With the decrease of mould temperature from 600 to 400 °C and then to 200 °C and finally to room temperature, primary Mg2 Si transformed from a mixture of an equiaxed-dendrite and an octahedron to a truncated octahedron and then to a truncated cube and finally to a cube; in contrast, primary Mg2 Si still remained dendritic in the Ca-free Al–20Mg2 Si alloy. Moreover, the skeleton-type growth process of the truncated cubic primary Mg2 Si in the modified alloy was identified, where growth steps with some hillocks were observed for the first time. Our study offers a simple and low-cost method to control the morphology and size of primary Mg2 Si crystals in the Al–Mg–Si alloy, which is beneficial to the design of lightweight Al–Mg–Si alloys with high strength and toughness.