C–H⋯Cl− hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands. Issue 12 (30th January 2017)

• Record Type: Journal Article
• Authors: Ikeda, Mari; Sah, Ajay Kumar; Iwase, Miki; Murashige, Rina; Ishi-i, Jun-ichi; Hasegawa, Masatoshi; Kachi-Terajima, Chihiro; Park, Ki-Min; Kuwahara, Shunsuke; Habata, Yoichi
• Is Part Of: Dalton transactions. Volume 46:Issue 12(2017)
• Page Start: 3800
• Page End: 3804
• Publication Date: 2017-01-30
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt03390c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Structural evidence is reported for C–H⋯Cl − hydrogen bonds in solution and in the solid state of cyclen-based cryptands/HgCl2 complexes. Abstract : Structural evidence is reported for C–H⋯Cl − hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1 ) and (2 ) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the2 /HgCl2 complex contains an acetonitrile molecule in the cavity.