One-pot synthesis of benzazoles and quinazolinones via iron pentacarbonyl mediated carbonylation of aryl iodides under microwave irradiation. Issue 3 (21st December 2016)

• Record Type: Journal Article
• Authors: Lin, Wun-Huei; Wu, Wen-Chun; Selvaraju, Manikandan; Sun, Chung-Ming
• Is Part Of: Organic chemistry frontiers. Volume 4:Issue 3(2017)
• Page Start: 392
• Page End: 397
• Publication Date: 2016-12-21
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c6qo00733c
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : A direct and unconventional method for the synthesis of benzazoles and quinazolinones is discovered by using iron pentacarbonyl as a reducing agent and a solid carbon monoxide source under microwave irradiation. Abstract : A direct and unconventional method for the synthesis of benzazoles and quinazolinones is discovered by using iron pentacarbonyl as a reducing agent and a carbon monoxide source under microwave irradiation. The reaction of substituted aryl iodides with o -amino/mercapto/hydroxyl nitrobenzenes and o -nitrobenzamides successfully delivered a wide variety of benzazoles and quinazolinones, respectively.