Self-sacrificed synthesis of carbon-coated SiOx nanowires for high capacity lithium ion battery anodes. Issue 8 (6th February 2017)

• Record Type: Journal Article
• Authors: Li, Zhaohuai; He, Qiu; He, Liang; Hu, Ping; Li, Wei; Yan, Haowu; Peng, Xianzhou; Huang, Congyun; Mai, Liqiang
• Is Part Of: Journal of materials chemistry. Volume 5:Issue 8(2017)
• Page Start: 4183
• Page End: 4189
• Publication Date: 2017-02-06
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c6ta10583a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Carbon-coated SiO x nanowires are synthesized through a novel self-sacrificed method and applied for high-performance LIB anodes. Abstract : Silicon oxide (SiO x ) shows great potential for lithium ion battery (LIB) anodes due to its high capacity, environmental friendliness, low cost and high abundance. Herein, we used low-cost mesoporous silica spheres to synthesize core–shell structured porous carbon-coated SiO x nanowires (pC–SiO x NWs) as a new LIB anode through a novel self-sacrificed method. The one-dimensional structure can accommodate large volume expansion without breaking. The porous carbon coating hinders the penetration of the electrolyte into pC–SiO x NWs and formation of a stable solid-electrolyte interphase (SEI) film on the external surface of pC–SiO x NWs. As a result, the composite shows excellent cycling stability with high reversible specific capacities of 1060 mA h g −1 (100 cycles) and 623 mA h g −1 (150 cycles) at current densities of 100 mA g −1 and 500 mA g −1, respectively. The proposed facile and scalable synthesis is highly competitive for large-scale applications in lithium storage devices/systems.