C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Issue 4 (22nd December 2016)
- Record Type:
- Journal Article
- Title:
- C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Issue 4 (22nd December 2016)
- Main Title:
- C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene
- Authors:
- Emerson-King, Jack
Hauser, Simone A.
Chaplin, Adrian B. - Abstract:
- Abstract : IBioxMe4 enacts selective single and double C–F bond activation of octafluorotoluene and hexafluorobenzene, respectively. Abstract : The N-heterocyclic carbene IBioxMe4 enacts selective single and double C–F bond activation of octafluorotoluene and hexafluorobenzene, respectively. The formation of the fluoroarene substituted, zwitterionic imidazoliumolate products is consistent with a mechanism involving nucleophilic aromatic substitution and subsequent oxazoline ring opening by liberated fluoride.
- Is Part Of:
- Organic & biomolecular chemistry. Volume 15:Issue 4(2017)
- Journal:
- Organic & biomolecular chemistry
- Issue:
- Volume 15:Issue 4(2017)
- Issue Display:
- Volume 15, Issue 4 (2017)
- Year:
- 2017
- Volume:
- 15
- Issue:
- 4
- Issue Sort Value:
- 2017-0015-0004-0000
- Page Start:
- 787
- Page End:
- 789
- Publication Date:
- 2016-12-22
- Subjects:
- Chemistry, Organic -- Periodicals
Bioorganic chemistry -- Periodicals
Chemistry, Physical organic -- Periodicals
547 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/ob#!recentarticles&all ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6ob02556k ↗
- Languages:
- English
- ISSNs:
- 1477-0520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6286.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 648.xml