From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis. Issue 2 (5th December 2016)

• Record Type: Journal Article
• Authors: Adler, Pauline; Fadel, Antoine; Prunet, Joëlle; Rabasso, Nicolas
• Is Part Of: Organic & biomolecular chemistry. Volume 15:Issue 2(2017)
• Page Start: 387
• Page End: 395
• Publication Date: 2016-12-05
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c6ob02548j
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : Acyclic α-amino vinylphosphonates were alkylated through the Mitsunobu reaction then diolefinic compounds hence formed were subjected to RCM. Abstract : Acyclic α-amino vinylphosphonates were alkylated through the Mitsunobu reaction then diolefinic compounds hence formed were subjected to RCM. Studies on the scope and limitations of RCM with these sterically hindered α-amino vinylphosphonates are detailed.