The stabilization of gallane and indane by a ring expanded carbene. Issue 2 (27th November 2014)

• Record Type: Journal Article
• Authors: Leverett, Anthony R.; McKay, Alasdair I.; Cole, Marcus L.
• Is Part Of: Dalton transactions. Volume 44:Issue 2(2015)
• Page Start: 498
• Page End: 500
• Publication Date: 2014-11-27
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03489a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : 7Dipp Complexes of GaH3 and InH3 have been prepared. Despite high thermal stability in the solid state, both adducts decompose readily in solution at ambient temperature. Abstract : 7Dipp Complexes of the group 13 binary hydrides GaH3 and InH3 have been prepared. Both adducts possess excellent thermal stability in the solid state but decompose readily in solution at ambient temperature. The presence of short M–H⋯H–CAlkyl distances in the structures of both [MH3 (7Dipp)] complexes is discussed.