BaCu2Se2 based compounds as promising thermoelectric materials. Issue 5 (22nd December 2014)

• Record Type: Journal Article
• Authors: Li, Jing; Zhao, Li-Dong; Sui, Jiehe; Berardan, David; Cai, Wei; Dragoe, Nita
• Is Part Of: Dalton transactions. Volume 44:Issue 5(2015)
• Page Start: 2285
• Page End: 2293
• Publication Date: 2014-12-22
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03556a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The thermoelectric properties of Na doped BaCu2 Se2 were studied. The electrical conductivity of BaCu2 Se2 was increased by 2 orders of magnitude through Na doping at the Ba sites, combined with a surprisingly low thermal conductivity; a ZT of 1.0 has been obtained for Ba0.925 Na0.075 Cu2 Se2 at 773 K. Abstract : In the past few years, many studies have been devoted to the thermoelectric properties of copper selenides and sulfides, and several families of materials have been developed with promising performances. In this paper, we report on the synthesis and thermoelectric properties of Na-doped BaCu2 Se2 from 20 K to 773 K. By Na doping at the Ba site, the electrical conductivity can be increased by 2 orders of magnitude, and the power factor can reach 8.2 μW cm −1 K −2 at 773 K. Combined with a low thermal conductivity of 0.65 W m −1 K −1, a ZT of 1.0 has been obtained for Ba0.925 Na0.075 Cu2 Se2 at 773 K, which is the highest value reported in this family to date. However, BaCu2 Se2 volatilizes at 473 K, so a protective coating is necessary for its application. Besides, we studied the thermal expansion coefficient of BaCu2 Se2 in this paper.