Photogeneration of two reduction-active charge-separated states in a hybrid crystal of polyoxometalates and naphthalene diimides. Issue 2 (24th November 2014)

• Record Type: Journal Article
• Authors: Liu, Jian-Jun; Wang, Yao; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin
• Is Part Of: Dalton transactions. Volume 44:Issue 2(2015)
• Page Start: 484
• Page End: 487
• Publication Date: 2014-11-24
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03029j
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Upon irradiation, two kinds of long-lived charge-separated states for the reduction reactions can be generated in a hybrid crystal composed of two-dimensional naphthalene diimide coordination networks and polyoxometalates. Abstract : The combination of naphthalene diimide tectons with zinc cations in the presence of polyanions, Mo6 O19 2−, leads to a hybrid crystal composed of two-dimensional porous coordination networks and polyoxometalates, which can generate two kinds of long-lived charge-separated states for the reduction reactions upon irradiation.