[RuV(NCN-Me)(bpy)(O)]3+ Mediates efficient C–H bond oxidation from NADH analogs in aqueous media rather than water oxidation. Issue 3 (5th December 2014)

• Record Type: Journal Article
• Authors: Patel, Jully; Majee, Karunamay; Ahmạd, Ejaz; Tanaka, Koji; Padhi, Sumanta Kumar
• Is Part Of: Dalton transactions. Volume 44:Issue 3(2015)
• Page Start: 920
• Page End: 923
• Publication Date: 2014-12-05
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt02827a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The [Ru V O] 3+ and [Ru VI O] 4+ generated from [Ru II (NCN-Me)(bpy)(H2 O)](PF6 )2 play the selective role in C–H bond oxidation of 2-(pyridin-2-yl)-9, 10-dihydroacridine (PADHH) and water splitting, respectively, are reported. Abstract : [Ru V O] 3+ and [Ru VI O] 4+ generated from [Ru II (NCN-Me)(bpy)(H2 O)](PF6 )2 (where NCN-Me is the neutral N -methyl-3, 5-di(2-pyridyl)pyridinium iodide after deprotonation of the C–H bond) play a selective role in the C–H bond oxidation of 2-(pyridin-2-yl)-9, 10-dihydroacridine (PADHH) and water oxidation, respectively.