A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels. Issue 3 (1st December 2014)

• Record Type: Journal Article
• Authors: Feng, Yuquan; Li, Min; Fan, Huitao; Huang, Qunzeng; Qiu, Dongfang; Shi, Hengzhen
• Is Part Of: Dalton transactions. Volume 44:Issue 3(2015)
• Page Start: 894
• Page End: 897
• Publication Date: 2014-12-01
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt02840f
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The open-framework copper borophosphate not only features novel borophosphate anionic partial structure containing 1-D 12-MR channels, but also exhibits ferromagnetic interactions and high catalytic activity for the oxidative degradation of chitosan. Abstract : A novel open-framework copper borophosphate, Na5 KCu3 [B9 P6 O33 (OH)3 ]·H2 O (1 ), has been synthesised by a boric acid flux method. Its structure can be viewed as a 3-D open framework constructed by the connection of Cu II O6 octahedra and 1-D (4, 4)-connected borophosphate anionic structures composed of trigonal-planar BO2 (OH) groups, tetrahedral BO4 and PO4 groups. The compound not only features a novel borophosphate anionic partial structure containing 1-D 12-MR channels, but also exhibits ferromagnetic interactions and high catalytic activity for the oxidative degradation of chitosan.