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Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and CC bonds with B(C6F5)3 and boryl–borate lithium. Issue 25 (24th November 2014)
Record Type:
Journal Article
Title:
Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and CC bonds with B(C6F5)3 and boryl–borate lithium. Issue 25 (24th November 2014)
Main Title:
Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and CC bonds with B(C6F5)3 and boryl–borate lithium
Abstract : The frustrated Lewis pair (FLP) comprised of boryl–borate lithium [pinBB(Ph)pin]Li and B(C6 F5 )3 can efficiently activate H2, HBpin and C2 H4 . Abstract : The frustrated Lewis pair comprised of B(C6 F5 )3 and a boryl–borate lithium salt Li[pinBB(Ph)pin] can efficiently activate dihydrogen, pinacolborane and ethylene at ambient temperature. Theoretical studies suggest that the nucleophilic sp 2 boryl moiety of Li[pinBB(Ph)pin] plays different roles in these reactions.