A crystallographically characterized salt of self-generated N-protonated tetraethylurea. Issue 7 (8th December 2014)
- Record Type:
- Journal Article
- Title:
- A crystallographically characterized salt of self-generated N-protonated tetraethylurea. Issue 7 (8th December 2014)
- Main Title:
- A crystallographically characterized salt of self-generated N-protonated tetraethylurea
- Authors:
- Bortoluzzi, Marco
Marchetti, Fabio
Pampaloni, Guido
Zacchini, Stefano - Abstract:
- Abstract : The first crystallographically characterized N -protonated urea (1, 1, 3, 3-tetraethylurea, teu) was obtained by a WCl6 -directed electron transfer/C–H activation process. Abstract : The reaction of 1, 1, 3, 3-tetraethylurea (teu) with WCl6 in dichloromethane afforded [teuH][WCl6 ], 1, in 50–60% yield. The X-ray structure determined for1 includes the first example of crystallographic characterization of a N -protonated urea. According to spectroscopic and DFT outcomes, the formation of1 is the result of an electron transfer/C–H activation process.
- Is Part Of:
- Chemical communications. Volume 51:Issue 7(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 7(2015)
- Issue Display:
- Volume 51, Issue 7 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 7
- Issue Sort Value:
- 2015-0051-0007-0000
- Page Start:
- 1323
- Page End:
- 1325
- Publication Date:
- 2014-12-08
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c4cc08801h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
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