High finesse optical cavity coupled with a quartz-enhanced photoacoustic spectroscopic sensor. Issue 3 (3rd December 2014)

• Record Type: Journal Article
• Authors: Patimisco, Pietro; Borri, Simone; Galli, Iacopo; Mazzotti, Davide; Giusfredi, Giovanni; Akikusa, Naota; Yamanishi, Masamichi; Scamarcio, Gaetano; De Natale, Paolo; Spagnolo, Vincenzo
• Is Part Of: Analyst. Volume 140:Issue 3(2015)
• Page Start: 736
• Page End: 743
• Publication Date: 2014-12-03
• Subjects: Chemistry, Analytic -- Periodicals; 543
• DOI: 10.1039/c4an01158a
• Languages: English
• ISSNs: 0003-2654

Abstract

Abstract : An ultra-sensitive quartz-enhanced photoacoustic spectroscopy combined with a high-finesse cavity sensor platform is proposed as a novel gas sensing system. Abstract : An ultra-sensitive and selective quartz-enhanced photoacoustic spectroscopy (QEPAS) combined with a high-finesse cavity sensor platform is proposed as a novel method for trace gas sensing. We call this technique Intra-cavity QEPAS (I-QEPAS). In the proposed scheme, a single-mode continuous wave quantum cascade laser (QCL) is coupled into a bow-tie optical cavity. The cavity is locked to the QCL emission frequency by means of a feedback-locking loop that acts directly on a piezoelectric actuator mounted behind one of the cavity mirrors. A power enhancement factor of ∼240 was achieved, corresponding to an intracavity power of ∼0.72 W. CO2 was selected as the target gas to validate our sensor. For the P(42) CO2 absorption line, located at 2311.105 cm −1, a minimum detection limit of 300 parts per trillion by volume at a total gas pressure of 50 mbar was achieved with a 20 s integration time. This corresponds to a normalized noise equivalent absorption of 3.2 × 10 −10 W cm −1 Hz −1/2, comparable with the best results reported for the QEPAS technique on much faster relaxing gases. A comparison with standard QEPAS performed under the same experimental conditions confirms that the I-QEPAS sensitivity scales with the intracavity laser power enhancement factor.