Catalytic SNAr of unactivated aryl chlorides. Issue 14 (10th October 2014)
- Record Type:
- Journal Article
- Title:
- Catalytic SNAr of unactivated aryl chlorides. Issue 14 (10th October 2014)
- Main Title:
- Catalytic SNAr of unactivated aryl chlorides
- Authors:
- Walton, James W.
Williams, Jonathan M. J. - Abstract:
- Abstract : A catalytic cycle that involves a Ru(η 6 -arylchloride) intermediate facilitates nucleophilic aromatic substitution of an unactivated aryl chloride. Abstract : We present nucleophilic aromatic substitution of unsubstituted aryl chlorides via a mechanism that is catalytic in [CpRu( p -cymene)]PF6 and involves a Ru(η 6 -arylchloride) intermediate. From the spectroscopic evidence we infer that arene exchange is the rate limiting step in this process and develop several new Ru(ii ) complexes that lower the activation barrier to arene exchange.
- Is Part Of:
- Chemical communications. Volume 51:Issue 14(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 14(2015)
- Issue Display:
- Volume 51, Issue 14 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 14
- Issue Sort Value:
- 2015-0051-0014-0000
- Page Start:
- 2786
- Page End:
- 2789
- Publication Date:
- 2014-10-10
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c4cc07116f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 773.xml