Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi). Issue 25 (22nd December 2014)

• Record Type: Journal Article
• Authors: Woodall, Sean D.; Swinburne, Adam N.; lal Banik, Nidhu; Kerridge, Andrew; Di Pietro, Poppy; Adam, Christian; Kaden, Peter; Natrajan, Louise S.
• Is Part Of: Chemical communications. Volume 51:Issue 25(2015)
• Page Start: 5402
• Page End: 5405
• Publication Date: 2014-12-22
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c4cc08718f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The room temperature detection of neptunyl(vi ) LMCT emission in a coordination compound and in the presence of uranyl(vi ) is reported for the first time. Differences in the excitation profile of each complex enables spectral editing of the neptunyl(vi ) and uranyl(vi ) emission. Abstract : Room temperature detection of neptunyl(vi ) LMCT emission in a coordination compound and in the presence of uranyl(vi ) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(vi ) or uranyl(vi ) emission is observed or a sum of the two.