Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption. Issue 15 (8th February 2017)

• Record Type: Journal Article
• Authors: Li, Yun-Wu; Yan, Hui; Hu, Tong-Liang; Ma, Hui-Yan; Li, Da-Cheng; Wang, Su-Na; Yao, Qing-Xia; Dou, Jian-Min; Xu, Jian; Bu, Xian-He
• Is Part Of: Chemical communications. Volume 53:Issue 15(2017)
• Page Start: 2394
• Page End: 2397
• Publication Date: 2017-02-08
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc09923h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic Fe/Na-chains as SBUs, respectively. Notably, both of them exhibit highly selective CO2 uptake over CH4 and N2 owing to abundant multiple active sites. Abstract : Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {Fe2 Na3 } n chains as SBUs, respectively. Both of them exhibit highly selective CO2 adsorption over CH4 and N2, owing to their abundant multiple active sites.