Sonochemical/hydration–dehydration synthesis of Pt–TiO2 NPs/decorated carbon nanotubes with enhanced photocatalytic hydrogen production activity. Issue 11 (28th September 2016)

• Record Type: Journal Article
• Authors: Abdulrazzak, Firas H.; Hussein, Falah H.; Alkaim, Ayad F.; Ivanova, Irina; Emeline, Alexei V.; Bahnemann, Detlef W.
• Is Part Of: Photochemical & photobiological sciences. Volume 15:Issue 11(2016:Nov.)
• Page Start: 1347
• Page End: 1357
• Publication Date: 2016-09-28
• Subjects: Photochemistry -- Periodicals; Photobiology -- Periodicals; 541.35
• DOI: 10.1039/c6pp00240d
• Languages: English
• ISSNs: 1474-905X

Abstract

Abstract : Modified Pt–TiO2 NPs/decorated carbon nanotubes were synthesized utilizing sonochemical/hydration–dehydration techniques. Abstract : Modified Pt–TiO2 NPs/decorated carbon nanotubes were synthesized utilizing sonochemical/hydration–dehydration techniques. Pt was loaded on TiO2 by a photodeposition method keeping in mind the end goal to achieve electron–hole pair separation and promote the surface reaction. The morphological and basic properties of Pt–TiO2 /fCNTs were investigated by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), UV–vis diffuse reflectance spectroscopy (DRS), photoluminescence (PL) and Raman spectroscopy. The selected area electron diffraction (SAED) patterns of Pt–TiO2 /fCNTs were obtained utilizing TEM-based energy dispersive X-ray spectroscopy (EDXS) analysis. It was found that the TiO2 nanoparticles were uniformly distributed on the fCNTs, and the Pt particles were decorated on the surface of TiO2 /fCNTs. The photocatalytic hydrogen production activity of the Pt(0.5%) –TiO2 /fCNTs(0.5%) nanoparticle composites was investigated using a sacrificial agent methanol solution. Pt-loaded TiO2 demonstrated a hydrogen evolution rate around 20 times that of TiO2 /fCNTs(0.5%) (fSWCNTs, fMWCNTs). When compared with platinized TiO2 in methanol, which was utilized as a control material, Pt–TiO2 /fCNTs demonstrated an almost 2-fold increment in hydrogen generation.