The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes. Issue 5 (25th November 2015)

• Record Type: Journal Article
• Authors: Fleming, James T.; Ficks, Arne; Waddell, Paul G.; Harrington, Ross W.; Higham, Lee J.
• Is Part Of: Dalton transactions. Volume 45:Issue 5(2016)
• Page Start: 1886
• Page End: 1890
• Publication Date: 2015-11-25
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt04475h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A series of enantiopure MOP-phosphonite ligands, with tailored steric profiles, have been synthesised and are proven to be very successful in high-yielding, regio- and enantioselective catalytic hydrosilylation reactions of substituted styrenes, affording important chiral secondary alcohols. Abstract : A series of enantiopure MOP-phosphonite ligands, with tailored steric profiles, have been synthesised and are proven to be very successful in high-yielding, regio- and enantioselective catalytic hydrosilylation reactions of substituted styrenes, affording important chiral secondary alcohols.