Optimizing and characterizing grating efficiency for a soft X‐ray emission spectrometer. (8th February 2013)

• Record Type: Journal Article
• Authors: Boots, Mark; Muir, David; Moewes, Alexander
• Is Part Of: Journal of synchrotron radiation. Volume 20:Part 2(2013)
• Page Start: 272
• Page End: 285
• Publication Date: 2013-02-08
• Subjects: diffraction grating -- grating efficiency -- soft X‐ray -- emission spectrometer; Synchrotron radiation -- Periodicals; Free electron lasers -- Periodicals; 539.73505
• DOI: 10.1107/S0909049512051266
• Languages: English
• ISSNs: 0909-0495

Abstract

Abstract : The efficiency of soft X‐ray diffraction gratings is studied using measurements and calculations based on the differential method with the S ‐matrix propagation algorithm. New open‐source software is introduced for efficiency modelling that accounts for arbitrary groove profiles, such as those based on atomic force microscopy (AFM) measurements; the software also exploits multi‐core processors and high‐performance computing resources for faster calculations. Insights from these calculations, including a new principle of optimal incidence angle, are used to design a soft X‐ray emission spectrometer with high efficiency and high resolution for the REIXS beamline at the Canadian Light Source: a theoretical grating efficiency above 10% and resolving power E /Δ E > 2500 over the energy range from 100 eV to 1000 eV are achieved. The design also exploits an efficiency peak in the third diffraction order to provide a high‐resolution mode offering E /Δ E > 14000 at 280 eV, and E /Δ E > 10000 at 710 eV, with theoretical grating efficiencies from 2% to 5%. The manufactured gratings are characterized using AFM measurements of the grooves and diffractometer measurements of the efficiency as a function of wavelength. The measured and theoretical efficiency spectra are compared, and the discrepancies are explained by accounting for real‐world effects: groove geometry errors, oxidation and surface roughness. A curve‐fitting process is used to invert the calculations to predict grating parameters that match the calculated and measured efficiency spectra; the predicted blaze angles are found to agree closely with the AFM estimates, and a method of characterizing grating parameters that are difficult or impossible to measure directly is suggested.