Characteristics of La0.6Sr0.4Co0.2Fe0.8O3–Cu2O mixture as a contact material in SOFC stacks. (12th January 2017) - Shong, Wei-Ja
Abstract: La0.6 Sr0.4 Co0.2 Fe0.8 O3 (LSCF), a cathode material for solid oxide fuel cells, is mixed with six weight percentages (2.46–21.74 wt%) of more conductive Cu2 O powder for use as a cathode contact material. Electrical conductivity change is measured at 800 °C for 600 h. Conductivity first increases with the Cu2 O weight percentage to reach a peak value 30.67 S/cm at 7.18 wt%, then decreases with further more Cu2 O content. Microstructural examination reveals that Cu2 O oxidizes as CuO in the high temperature environment with a loose matrix, which can raise the electrical resistance. LSCF–Cu2 O paste with three weight percentages of Cu2 O is also applied in steel/paste/steel assemblies. The area specific resistance is measured at 800 °C for 200–300 h. It is found that LSCF-7.18 wt% Cu2 O exhibits the lowest resistance. Additionally, stack performance is compared between two single-cell stacks with Ag mesh and LSCF-4.9 wt% CuO as the contact layer respectively. It shows that the LSCF-4.9 wt% CuO stack yields comparable power output with a lower degradation rate. Experimental results indicate that LSCF with 7.18 wt% Cu2 O addition can serve as a potential contact material. Highlights: Various compositions of LSCF–Cu2 O mixed powder are studied as contact materials. A composition with 7.18 wt% of Cu2 O yields highest conductivity. Excessive addition of Cu2 O causes significant mismatch of thermal expansion and decreases conductivity. LSCF with 7.18 wt% Cu2 O addition can serve as a potential contact material.