Grain boundary engineering in organic–inorganic hybrid semiconductor ZnS(en)0.5 for visible-light photocatalytic hydrogen production. Issue 4 (5th January 2017)

• Record Type: Journal Article
• Authors: Feng, Wenhui; Fang, Zhibin; Wang, Bo; Zhang, Lulu; Zhang, Yan; Yang, Yu; Huang, Mianli; Weng, Sunxian; Liu, Ping
• Is Part Of: Journal of materials chemistry. Volume 5:Issue 4(2017)
• Page Start: 1387
• Page End: 1393
• Publication Date: 2017-01-05
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c6ta09633f
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Unique grain boundary-rich organic–inorganic hybrid D-ZnS(en)0.5 nanosheets exhibit superior activity for photocatalytic H2 evolution under visible light irradiation. Abstract : A pile of unique grain boundary-engineered ZnS(en)0.5 nanosheets (D-ZnS(en)0.5 NSs) are constructed via a solvothermal process. Large amounts of stacking fault and dislocation in D-ZnS(en)0.5 at the boundaries could create mid-gap defect states, in which intraband transition and carrier creation are induced under visible light irradiation. Meanwhile, a defect-rich structure with a quasiperiodic configuration endows the integrated polycrystalline NSs with preferable electrical properties. Owing to the enriched defect-state excitation and optimized electrical properties, D-ZnS(en)0.5 exhibits superior visible-light-driven photocatalytic performance for hydrogen evolution from water. This work will provide a new strategy for achieving a visible-light organic–inorganic hybrid photocatalyst.