Copper(I)-mediated trifluoromethylthiolation of α-bromoketone with element sulfur and (trifluoromethyl)trimethylsilane. Issue 34 (26th August 2015)
- Record Type:
- Journal Article
- Title:
- Copper(I)-mediated trifluoromethylthiolation of α-bromoketone with element sulfur and (trifluoromethyl)trimethylsilane. Issue 34 (26th August 2015)
- Main Title:
- Copper(I)-mediated trifluoromethylthiolation of α-bromoketone with element sulfur and (trifluoromethyl)trimethylsilane
- Authors:
- Li, Jue
Xie, Fei-Fei
Wang, Peiqiang
Wu, Qiang-Yong
Chen, Wei-Dong
Ren, Jiangmeng
Zeng, Bu-Bing - Abstract:
- Abstract: A new method has been developed for the copper(I)-mediated trifluoromethylthiolation of α-bromoketone using commercial anhydrous potassium fluoride, elemental sulfur, and (trifluoromethyl)-trimethylsilane in anhydrous N, N -dimethylformamide. This protocol provides facile access to a variety of α-trifluoromethylthiolated carbonyl compounds in moderate to excellent yields under mild and ligand free conditions. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 34(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 34(2015)
- Issue Display:
- Volume 71, Issue 34 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 34
- Issue Sort Value:
- 2015-0071-0034-0000
- Page Start:
- 5520
- Page End:
- 5524
- Publication Date:
- 2015-08-26
- Subjects:
- Trifluoromethylthiolation -- α-Bromoketone -- Sulfur -- (Trifluoromethyl)trimethylsilane
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.06.068 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2516.xml