Copper-catalyzed selective C_O bond formation by oxidative α-C(sp3)_H/O_H coupling between ethers and salicylaldehydes. Issue 15 (15th April 2015)
- Record Type:
- Journal Article
- Title:
- Copper-catalyzed selective C_O bond formation by oxidative α-C(sp3)_H/O_H coupling between ethers and salicylaldehydes. Issue 15 (15th April 2015)
- Main Title:
- Copper-catalyzed selective C_O bond formation by oxidative α-C(sp3)_H/O_H coupling between ethers and salicylaldehydes
- Authors:
- Barve, Balaji D.
Wu, Yang-Chang
El-Shazly, Mohamed
Korinek, Michal
Cheng, Yuan-Bin
Wang, Jeh-Jeng
Chang, Fang-Rong - Abstract:
- Abstract: Copper-catalyzed oxidative coupling of ethers and salicylaldehydes, via the direct α-C(sp 3 )–H bond functionalization of ethers in the presence tert -butyl hydroperoxide as an oxidant has been explored. The corresponding acetals were selectively formed in moderate to excellent yields. The sensitive formyl group of salicylaldehydes remained intact despite the oxidative reaction conditions. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 15(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 15(2015)
- Issue Display:
- Volume 71, Issue 15 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 15
- Issue Sort Value:
- 2015-0071-0015-0000
- Page Start:
- 2290
- Page End:
- 2297
- Publication Date:
- 2015-04-15
- Subjects:
- Aldehydes -- Copper -- C–H functionalization -- Oxidation -- C–O bond formation
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.02.035 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1074.xml