Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF3 and TMSCF2CF3. Issue 41 (14th October 2015)
- Record Type:
- Journal Article
- Title:
- Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF3 and TMSCF2CF3. Issue 41 (14th October 2015)
- Main Title:
- Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF3 and TMSCF2CF3
- Authors:
- Jin, Guanyi
Zhang, Xuxue
Fu, Dan
Dai, Wenpeng
Cao, Song - Abstract:
- Abstract: A direct and efficient approach for the trifluoromethylation and pentafluoroethylation of 1, 1-diaryl-2, 2-difluoroethenes with TMSCF3 and TMSCF2 CF3 in the presence of TBAF was developed. The reactions proceeded smoothly under mild reaction conditions to give the corresponding monotrifluoromethylated, bistrifluoromethylated, monopentafluoroethylated and bispentafluoroethylated products in fair to good yields, respectively, without the addition of metal catalyst. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 41(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 41(2015)
- Issue Display:
- Volume 71, Issue 41 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 41
- Issue Sort Value:
- 2015-0071-0041-0000
- Page Start:
- 7892
- Page End:
- 7899
- Publication Date:
- 2015-10-14
- Subjects:
- Trifluoromethylation -- Pentafluoroethylation -- gem-Difluoroalkenes -- (Trifluoromethyl)trimethylsilane -- (Pentafluoroethyl)trimethylsilane
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.08.016 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1976.xml