Preparation of high-purity nano-CaCO3 from steel slag. (1st February 2017)

• Record Type: Journal Article
• Authors: Jo, Hoyong; Lee, Min-Gu; Park, Jinwon; Jung, Kwang-Deog
• Is Part Of: Energy. Volume 120(2017)
• Page Start: 884
• Page End: 894
• Publication Date: 2017-02-01
• Subjects: Steel slag -- Alkali metal ion dissolution -- Mineral carbonation -- Nano-CaCO3; Power resources -- Periodicals; Power (Mechanics) -- Periodicals; Energy consumption -- Periodicals; 333.7905
• DOI: 10.1016/j.energy.2016.11.140
• Languages: English
• ISSNs: 0360-5442

Abstract

Abstract: Indirect carbonation is a suitable method for carbon dioxide (CO2 ) removal from the environment, and it requires an acid to dissolve the calcium ions and a base to precipitate the formed calcium carbonate (CaCO3 ). We herein report a new method to produce high-purity nano-CaCO3 (nCaCO3 ) from steel slag using hydrochloric acid (HCl) and sodium hydroxide (NaOH). The rate equation for the dissolution of calcium (Ca) in the slag was derived using a range of variables, such as temperatures, solid-to-liquid (S/L) ratio, and HCl concentration. The purified calcium hydroxide (Ca(OH)2 ) was converted into nCaCO3 (size: 80–120 nm, purity: 98.5%) by carbonation with CO2, after impurities, such as iron (Fe), aluminum (Al), and Mg, were completely removed. An efficiency of 73% was obtained for the dissolution and precipitation steps when 0.50 M HCl and 1.0 M NaOH were employed to produce 1 ton/h of nano-CaCO3 with a purity of 98.5 wt%. Recently, a sodium chloride (NaCl) electrolysis system with low energy requirement was proposed to simultaneously produce HCl and NaOH. Assuming 90% faradic efficiency in the aforementioned NaCl electrolysis, process energies of 916 kWh/tCaCO3 and 1462 kWh/tCaCO3 were obtained at potentials of 0.83 V and 1.50 V, respectively. Highlights: A new carbonation process to prepare nano-sized CaCO3 from steel slag is proposed. Dissolution equations of Ca and Mg ions are presented. Purified nano-sized CaCO3 is produced by carbonation after a purification step. Energy consumption of coupled electrolysis-carbonation processes is calculated.