Inorganic dendrimers: recent advances for catalysis, nanomaterials, and nanomedicine. (3rd March 2016)

• Record Type: Journal Article
• Authors: Caminade, Anne-Marie
• Is Part Of: Chemical Society reviews. Volume 45:Number 19(2016:Oct.)
• Page Start: 5174
• Page End: 5186
• Publication Date: 2016-03-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cs00074f
• Languages: English
• ISSNs: 0306-0012

Abstract

Abstract : Among inorganic dendrimers, phosphorhydrazone dendrimers and carbosilane dendrimers are the most widely used as nanotools for catalysis, materials, and biology. Abstract : Dendrimers are hyperbranched polymers having a perfectly defined structure because they are synthesized step-by-step in an iterative fashion, and not by polymerization reactions. Some dendrimers are considered as inorganic, as they possess inorganic atoms at each branching point. Among numerous examples, two families of inorganic dendrimers have emerged as particularly promising: silicon-containing dendrimers, particularly carbosilanes, and phosphorus-containing dendrimers, particularly phosphorhydrazones. This tutorial review will display the main properties of both families of dendrimers in the fields of catalysis, materials and biology/nanomedicine. Emphasis will be put on the most recent and promising examples.