Rapid room temperature solubilization and depolymerization of polymeric lignin at high loadings. Issue 22 (20th October 2016)

• Record Type: Journal Article
• Authors: Sun, Jian; Dutta, Tanmoy; Parthasarathi, Ramakrishnan; Kim, Kwang Ho; Tolic, Nikola; Chu, Rosalie K.; Isern, Nancy G.; Cort, John R.; Simmons, Blake A.; Singh, Seema
• Is Part Of: Green chemistry. Volume 18:Issue 22(2016)
• Page Start: 6012
• Page End: 6020
• Publication Date: 2016-10-20
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/c6gc02258h
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : The relatively poor solubility of lignin in most pretreatment solvents remains one of the biggest challenges in lignin valorization to improve overall biorefinery economics. Abstract : The relatively poor solubility of lignin in most pretreatment solvents remains one of the biggest challenges in lignin valorization to improve overall biorefinery economics. In this work, rapid room temperature solubilization of lignin at high solid loadings (>30 wt%) can be easily achieved in a single step using ethylene glycol (EG). The solubilized lignin can be rapidly and quantitatively recovered with the addition of ethanol. The computational and nuclear magnetic resonance (NMR) spectroscopic studies confirm that strong hydrogen bond interactions between EG and the free hydroxyl groups present in lignin contribute to the lignin dissolution. In addition, hydrogen peroxide mediated depolymerization of the dissolved lignin at a low temperature (80 °C) was tested and the effect of EG molecules on depolymerization of lignin was also theoretically studied. The findings of this work provide mechanistic insights of hydrogen bond interactions in high lignin solubilization and valorization.