Surface modification of 316 stainless steel with platinum for the application of bipolar plates in high performance proton exchange membrane fuel cells. (26th January 2017)

• Record Type: Journal Article
• Authors: Lin, Kaijie; Li, Xiaoying; Dong, Hanshan; Du, Shangfeng; Lu, Yaxiang; Ji, Xiaochao; Gu, Dongdong
• Is Part Of: International journal of hydrogen energy. Volume 42:Number 4(2017)
• Page Start: 2338
• Page End: 2348
• Publication Date: 2017-01-26
• Subjects: 316 stainless steel -- Bipolar plates -- PEMFC -- Platinum -- Active screen plasma -- Single cell tests; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2016.09.220
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: 316 stainless steel has been regarded as one of the promising candidates to replace graphite for bipolar plate application. However, the relatively high electrical resistance caused by the formation of passive oxide film and the insufficient corrosion resistance in long-term operation are two main concerns of 316 stainless steel bipolar plates. Low temperature active screen plasma alloying technology shows the ability to reduce electrical resistance and enhance corrosion resistance of 316 stainless steel bipolar plates to some extent, but still can not satisfy the Department of Energy (DOE) requirements. In this paper, active screen plasma co-alloying treatments with nitrogen and platinum are conducted to modify the surface of 316 stainless steel. The surface morphology, phase constitute, chemical composition and layer structure of treated 316 stainless steel are fully studied. A dense, columnar structured and single phase Pt3 Fe deposition layer is produced on the surface of 316 stainless steel after treatments. Thanks to the excellent electrical conductivity and corrosion resistance of Pt3 Fe, the surface electrical conductivity and corrosion resistance are greatly enhanced and satisfies the DOE requirements, contributing to the significant improvement of single cell performances. Highlights: The surface of 316 stainless steel bipolar plates was modified with Pt. A dense, columnar structured and single phase Pt3 Fe deposition layer was produced. The Pt3 Fe deposition layers were characterised by SEM, XRD, TEM and XPS. The corrosion behaviour and ICR value met the DOE 2020 target for bipolar plates. The single cell performance of bipolar plates was largely improved after treatments.