Conductive poly(high internal phase emulsion) foams incorporated with polydopamine-coated carbon nanotubes. (10th February 2017)

• Record Type: Journal Article
• Authors: Kim, Haseung; Ahn, Kyung Hyun; Lee, Seong Jae
• Is Part Of: Polymer. Volume 110(2017)
• Page Start: 187
• Page End: 195
• Publication Date: 2017-02-10
• Subjects: Electrically conductive foam -- High internal phase emulsion -- Polydopamine-coated carbon nanotube; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2017.01.007
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: Electrically conductive poly(high internal phase emulsion) (polyHIPE) nanocomposite foams based on poly(styrene-co-divinylbenzene) were prepared by incorporating polydopamine-coated carbon nanotubes (PDA-CNTs). Conductive yet amphiphobic CNTs were modified to PDA-CNTs by coating with PDA on the surface of CNTs to provide hydrophilicity. As a result, it was possible to prepare highly stable HIPEs having PDA-CNT content >10 wt% and resultant polyHIPE foams having enhanced conductivity due to the good dispersion of PDA-CNTs in aqueous phase. The foams made with a water-to-monomer ratio of 10:1 showed well-developed interconnected microcellular structure. With increasing PDA-CNT content, the yield stress and storage modulus of HIPE increased and the cell size of the polyHIPE foam decreased. The electrical percolation threshold was determined to be less than PDA-CNT 1 wt% and the conductivity at PDA-CNT content of 8 wt% was increased to as high as 10 −2 Sm −1 . Surface modification of CNTs by PDA was very effective in providing electrical conductivity due to their stable dispersion in aqueous phase while keeping the intrinsic properties of CNTs intact. Graphical abstract: Highlights: Electrically conductive poly(high internal phase emulsion) foams are prepared. Polydopamine-coated carbon nanotubes are effective in providing conductivity. Highly stable HIPEs are made possible by excellent dispersion of the CNTs. The cell size of poly(HIPE) foams decreases with increasing the CNT content.