Control of bulk homochirality and proton conductivity in isostructural chiral metal–organic frameworks. Issue 11 (23rd January 2017)

• Record Type: Journal Article
• Authors: Song, Bai-Qiao; Chen, Da-Qin; Ji, Zhenguo; Tang, Junhong; Wang, Xin-Long; Zang, Hong-Ying; Su, Zhong-Min
• Is Part Of: Chemical communications. Volume 53:Issue 11(2017)
• Page Start: 1892
• Page End: 1895
• Publication Date: 2017-01-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc07729c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Two enantiomeric pairs of isostructural homochiral metal–organic frameworks (MOFs) have been synthesized directly from chiral ligands and indirectly from achiral ligands via spontaneous resolution combined with cooperative chirality induction, respectively. Abstract : We have demonstrated for the first time that isostructural homochiral metal–organic frameworks (MOFs) can be synthesized directly from chiral ligands and indirectly from achiral ligands via spontaneous resolution combined with cooperative chirality induction, respectively. Moreover, the usage of different ligands leads to distinct proton conduction behaviors.