Electrodeposition of compact zinc from the hydrophobic Brønsted acidic ionic liquid-based electrolytes and the study of zinc stability along with the acidity manipulation. (10th February 2017)

• Record Type: Journal Article
• Authors: Chen, Yi-Han; Yeh, Hsin-Wen; Lo, Nai-Chang; Chiu, Chen-Wei; Sun, I-Wen; Chen, Po-Yu
• Is Part Of: Electrochimica acta. Volume 227(2017)
• Page Start: 185
• Page End: 193
• Publication Date: 2017-02-10
• Subjects: Betaine -- Brønsted acidic -- Electrodeposition -- Ionic liquid -- Zinc stability; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.01.013
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical Abstract: Highlights: Compact Zn with no crack is deposited from protic ionic liquid-based electrolytes. The ionic liquid is composed of the protonated betaine ion. This ionic liquid is hydrophobic and zinc oxide is soluble in it. The effects of co-solvents, propylene carbonate and water, are studied. The Zn stripping/deposition efficiency can be manipulated via acidity adjustment. Abstract: Compact crystalline zinc was electrodeposited on stainless-steel electrode (SS) via potentiostatic/galvanostatic electrolysis from the hydrophobic Brønsted acidic ionic liquid, protonated betaine bis((trifluoromethyl)sulfonyl)imide (IL [Hbet][TFSI]), −based electrolytes containing ZnCl2 or ZnO under argon or ambient air atmosphere. Approximate 10 wt% of propylene carbonate and water, respectively, were used as the co-solvents for [Hbet][TFSI] to form the IL-based electrolytes. The efficiency of zinc deposition/stripping, which is significantly affected by the Brønsted acidity of the IL-based electrolytes, was studied at glassy carbon electrode (GC) to evaluate the stability of the zinc electrodeposits along with the electrolyte acidity. The stability is very poor for the zinc electrodeposits obtained from ZnCl2 solution. However, it increases with increasing the quantity of ZnO or urea in the electrolytes; the former neutralize the dissociable protons in [Hbet] cations to form water, and the latter may form H-bonding with [Hbet] or be protonated to form the weakly acidic cations [HUrea]. Both suppress the reaction between the Zn electrodeposits and protons. The stability of the Zn electrodeposits, therefore, can be improved via the manipulation of the IL acidity.